Contacts:
Supervisor(s):
Prof. Alessandra Operamolla
Title of the PhD project:
Extraction of cellulose nanocrystals or nanofibers from waste lignocellulosic biomass with potential protective properties for textile and/or bio-composite applications
Abstract of the PhD project:
The aim of the project is to extract cellulose nanocrystals or nanofibres from waste lignocellulosic biomass (like hemp, asclepia, kapok, kenaf and others, including biomass co-products and by-products derived from their collection) and use the nanocrystals and nanofibres as coating for textiles. Combination of the nanocrystals with other bio-based active molecules to enhance protection properties of the coating is a goal of the project. The research activity will be carried out at the Department of Chemistry and Industrial Chemistry, Grenoble INP and Pangaia- Grado Zero srl.
Publications:
• Nanocellulose for Paper and Textile Coating:The Importance of Surface Chemistry, L. Spagnuolo, R. D’Orsi, A. Operamolla, ChemPlusChem, 2022,87, https://doi.org/10.1002/cplu.202200204
• Materiali lignocellulosici avanzati, R. D’Orsi, L. Spagnuolo, A. Operamolla, La chimica e l’industria online | anno VI | n° 4 | luglio/agosto 2022, DOI: http://dx.medra.org/10.17374/CI.2022.104.4.66
• L. Spagnuolo, D. Beneventi, A. Dufresne, A. Operamolla, High Yield Synthesis of Cellulose Nanocrystals from Avicel by Mechano-Enzymatic Approach, ChemistrySelect, 2024, ChemistrySelect 2024, 9, e202401511
• L. Spagnuolo, L. Micheli, A. Dufresne, D. Beneventi, A. Operamolla, Covalent Lysozyme Immobilization on Enzymatic CelluloseNanocrystals, Chem. Eur. J. 2024, e202402171
• K. Matura, R. D’Orsi, L. Spagnuolo, F. Mayra, M. Cobet, C. Putz, A. Operamolla, S. Tekoglu, J. Mater. Chem. C, 2024, Advance Article
Oral communications at conferences:
• Self-assembly of enzymes on negatively charged cellulose nanocrystals, L. Spagnuolo, R. D’Orsi, L. Micheli, A. Operamolla, COST Chemobrionics Pisa Annual Meeting 2022. Time & Location. 05 Sept, 08:00 – 07 Sept, 20:00. Pisa, Pisa, Province of Pisa, flash presentation.
• Holistic enzymatic approach for cellulose nanocrystals preparation and functionalization toward antibacterial materials, L. Spagnuolo, R. D’Orsi, L. Micheli, A. Dufresne, A. Operamolla, CINMPIS days, Pisa, 9-11/02/2023, oral communication.
• Synthesis of immobilized biocatalysts on enzyme-driven nanostructured materials, A. Corbella international summer school ISOS24, Gargnano 16-21/06/2024,short oral communication.
• Enhancing Biocatalyst Performance: The Potential of Enzyme-Driven Nanostructured Materials, CFF 2024 - Chemistry for the Future International Conference, 3-5 July, 2024; key note.
• "Enzyme-Driven Nanostructured Materials: A Promise for Biocatalyst Immobilization and Activation" , L. Spagnuolo, L. Micheli, A. Dufresne, D. Beneventi , A. Operamolla, "SCI2024 XXVIII Congresso Nazionale della Società Chimica Italiana", Milano 26-30/08/2024, oral communication.
Poster communications at conferences:
• Extraction of cellulose nanocrystals from lignocellulosic biomass: application of chemical and enzymatic hydrolysis., CFF 2022 - Chemistry for the Future International Conference, June 29 - July 1, 2022; poster.
• Self-assembly of enzymes on negatively charged cellulose nanocrystals, L. Spagnuolo, R. D’Orsi, L. Micheli, A. Operamolla, COST Chemobrionics Pisa Annual Meeting 2022. Time & Location. 05 Sept, 08:00 – 07 Sept, 20:00. Pisa, Pisa, Province of Pisa, poster and flash presentation.
• Holistic enzymatic approach for cellulose nanocrystals preparation and functionalization toward antibacterial materials, L. Spagnuolo, R. D’Orsi, L. Micheli, A. Dufresne, A. Operamolla, CFF 2023 - Chemistry for the Future International Conference, June 27 - 30, 2023; poster.
• Self-assembly of lysozyme on cellulose nanocrystals for sustainable antibacterial materials , L. Spagnuolo, A. Dufresne, D.Beneventi, L. Micheli, A. Operamolla, European winter school on physical organic chemistry E-WISPOC24, 4-9/02/2024, Bressanone (BZ);poster.
Other achievements:
• Finalista del contest “ChiMiCapisce? 2024”, 24 maggio 2024, Roma.
