Contacts:
E-mail:
ResearchGate: https://www.researchgate.net/profile/Gianluca_Casotti
Google Scholar: https://scholar.google.com/citations?user=VIgeHtkAAAAJ
ORCID: http://orcid.org/0000-0002-2255-4077
ResearcherID: https://publons.com/researcher/W-1026-2018
Scopus ID: 57202899698
Supervisors:
Prof. Anna Iuliano
Title:
New protocols for the chemo-, regio- and stereoselective formation of C - C bonds via organometallics also by using innovative synthetic techniques.
Publications:
1. Fusini, G.; Barsanti, D.; Angelici, G.; Casotti, G.; Canale, A.; Benelli, G.; Lucchi, A.; Carpita, A. Identification and Synthesis of New Sex-Specific Components of Olive Fruit Fly ( Bactrocera Oleae ) Female Rectal Gland, through Original Negishi Reactions on Supported Catalysts. Tetrahedron 2018, 74 (33), 4381–4389. https://doi.org/10.1016/j.tet.2018.07.003.
2. Casotti, G.; Iuliano, A.; Carpita, A. Arylzinc Halides by Silver Catalyzed Zinc Insertion into Aryl Iodides. European J. Org. Chem. 2019, 2019 (5), 1021–1026. https://doi.org/10.1002/ejoc.201801543.
3. Rossi, R.; Angelici, G.; Casotti, G.; Manzini, C.; Lessi, M. Catalytic Synthesis of 1,2,4,5‐Tetrasubstituted 1 H ‐Imidazole Derivatives: State of the Art. Adv. Synth. Catal. 2019, adsc.201801381. https://doi.org/10.1002/adsc.201801381.
4. Laudadio, G.; Fusini, G.; Casotti, G.; Evangelisti, C.; Angelici, G.; Carpita, A. Synthesis of Pterostilbene through Supported-Catalyst Promoted Mizoroki-Heck Reaction, and Its Transposition in Continuous Flow Reactor. J. Flow Chem. 2019, 9 (2), 133–143. https://doi.org/10.1007/s41981-019-00033-0.
5. Casotti, G.; Ciancaleoni, G.; Lipparini, F.; Nieri, C.; Iuliano, A. Uncatalyzed Conjugate Addition of Organozinc Halides to Enones in DME: A Combined Experimental/Computational Study on the Role of the Solvent and the Reaction Mechanism. Chem. Sci. 2020, 11 (1), 257–263. https://10.1039/C9SC04820K.
6. Casotti, G.; Fusini, G.; Ferreri, M.; Pardini, L. F.; Evangelisti, C.; Angelici, G.; Carpita, A. Total Synthesis of Asparenydiol by Two Sonogashira Cross-Coupling Reactions Promoted by Supported Pd and Cu Catalysts. Synthesis 2020, 52 (12), 1795–1803. https://10.1055/s-0039-1690852.
7. Thakore, R. R.; Takale, B. S.; Casotti, G.; Gao, E. S.; Jin, H. S.; Lipshutz, B. H. Chemoselective Reductive Aminations in Aqueous Nanoreactors Using Parts per Million Level Pd/C Catalysis. Org. Lett. 2020, 22 (16), 6324–6329. https://10.1021/acs.orglett.0c02156.
8. Lipshutz, B. H.; Takale, B. S.; Thakore, R. R.; Casotti, G.; Li, X.; Gallou, F. Mild and Robust Stille Reactions in Water Using Ppm Levels of a New Triphenylphosphine‐based Palladacycle. Angew. Chemie Int. Ed. 2020, anie.202014141. https://10.1002/anie.202014141.
9. Casotti, G.; Rositano, V.; Iuliano, A. Enantioselective Conjugate Addition of Stabilized Arylzinc Iodide to Enones: An Improved Protocol of the Hayashi Reaction. Adv. Synth. Catal. 2020, adsc.202001141. https://10.1002/adsc.202001141.
Oral communications at congress:
1. Casotti, G.; Nieri, C.; Carpita; Iuliano, A., Uncatalyzed organozinc halides conjugate addition to enones, Rimini (Italy), 19 - 21 November 2018, Merck & Elsevier Young Chemists Symposium 2018 (MEYCS 2018).
2. Casotti, G.; Rositano, V.; Iuliano, A. Enantioselective conjugate addition of stabilized arylzinc halides to enones, Rimini (Italy), 25 - 27 November 2019, Merck Young Chemists Symposium 2019 (MYCS 2019).
Poster communications at congress:
1. Casotti, G.; Iuliano, A.; Carpita, Arylzinc Halides by Silver Catalyzed Zinc Insertion into Aryl Iodides, Gargnano (Italy), 10 - 14 June 2018, XLIII "A. Corbella" International Summer School on Organic Synthesis (ISOS 2018)
2. Casotti, G.; Iuliano, A.; Carpita, Arylzinc Halides by Silver Catalyzed Zinc Insertion into Aryl Iodides, Pisa (Italy), 4 - 6 July 2018, Chemistry For the Future 2018 (CFF 2018)
3. Casotti, G.; Iuliano, A.; Carpita, Preparation of arylzinc halides by silver promoted oxidative metalation, Florence (Italy), 18 - 20 July 2018, XIII Congresso del Gruppo Interdivisionale di Chimica Organometallica (CoGICO 2018)
4. Casotti, G.; Nieri, C.; Carpita; Iuliano, A., Uncatalyzed organozinc halides conjugate addition to enones, Rimini (Italy), 19 - 21 November 2018, Merck & Elsevier Young Chemists Symposium 2018 (MEYCS 2018)
